Burnt sienna is an iron oxide pigment: a warm mid brown color. Chemically, burnt sienna is formed by burning raw sienna (Terra di Sienna).
I use this color all the time. Many of my artist friends hate it but then again they also think Sargent is a great artist. Burnt sienna is a color that is always welcome on my palette while Sargent is not allowed onto my bookshelf. I use Burnt Umber when I do my underpaintings. Generally pigments that are made from iron oxides etc are cheaper and not as expensive as other colors. If you are a computer hack you don not need to bother buying paint at all.
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